Synthesis of polyaniline-intercalated layered materials via exchange reaction

被引:79
作者
Matsuo, Y
Higashika, S
Kimura, K
Miyamoto, Y
Fukutsuka, T
Sugie, Y
机构
[1] Himeji Inst Technol, Dept Appl Chem, Himeji, Hyogo 6712201, Japan
[2] Nichirin Co Ltd, Himeji, Hyogo 6710224, Japan
关键词
D O I
10.1039/b107436a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Polyaniline (PANI)-intercalated graphite oxides (GOs) or FeOCl were synthesized via exchange reaction of n-hexadecylamine- intercalated graphite oxides or FeOCl by PANI in an organic solvent. PANI-intercalated GOs with interlayer spacings (I-c values) of 1.14-1.68 nm and compositions of (PANI)(1.1-5.0)GO were obtained, depending on the amine contents in the starting materials. On the other hand, only one type of intercalation compound was successfully obtained for FeOCl with the composition (PANI)(0.42)FeOCl without excess PANI particles deposited on the surface. A structure model for the intercalated PANI chains in (PANI)(5.0)GO with I-c = 1.68 nm has been proposed: a double layer of PANI chains with their benzene rings parallel to the GO layer.
引用
收藏
页码:1592 / 1596
页数:5
相关论文
共 37 条
  • [1] BETA-TYPE INTERLAMELLAR SORPTION COMPLEXES
    ARAGON, F
    RUIZ, JC
    MACEWAN, DMC
    [J]. NATURE, 1959, 183 (4663) : 740 - 741
  • [2] INCLUSION OF POLY(ANILINE) INTO MOO3
    BISSESSUR, R
    DEGROOT, DC
    SCHINDLER, JL
    KANNEWURF, CR
    KANATZIDIS, MG
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (08) : 687 - 689
  • [3] INTERCALATION AND OXIDATIVE POLYMERIZATION OF ANILINE IN ZIRCONIUM-PHOSPHATES
    CHAO, KJ
    CHANG, TC
    HO, SY
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 1993, 3 (04) : 427 - 428
  • [4] Charge-discharge characteristic of polyaniline intercalated graphite oxide
    Higashika, S
    Kimura, K
    Matsuo, Y
    Sugie, Y
    [J]. ELECTROCHEMISTRY, 2001, 69 (07) : 530 - 535
  • [5] Synthesis of polyaniline-intercalated graphite oxide
    Higashika, S
    Kimura, K
    Matsuo, Y
    Sugie, Y
    [J]. CARBON, 1999, 37 (02) : 354 - 356
  • [6] Higashika S., 1999, TANSO, V160, P171
  • [7] SYNTHESIS OF A POLYANILINE INORGANIC NANOCOMPOSITE
    HILL, PG
    FOOT, PJS
    DAVIS, R
    [J]. NEW MATERIALS: CONJUGATED DOUBLE BOND SYSTEMS, 1995, 191 : 43 - 46
  • [8] Polymerization of aniline on copper phosphonate materials
    Hix, GB
    Maddocks, VC
    Harris, KDM
    [J]. POLYHEDRON, 2000, 19 (07) : 765 - 770
  • [9] Chemical and electrochemical characterization of a novel nanocomposite formed from V2O5 and Poly(N-propane sulfonic acid aniline), a self-doped polyaniline
    Huguenin, F
    Gambardella, MTD
    Torresi, RM
    de Torresi, SI
    Buttry, DA
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (07) : 2437 - 2444
  • [10] PREPARATION OF GRAPHITIC OXIDE
    HUMMERS, WS
    OFFEMAN, RE
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) : 1339 - 1339