Dimethyl malonate as a one-carbon source: a novel method of introducing carbon substituents onto aromatic nitro compounds

被引：33

作者：

Selvakumar, N ^{[1
]}

Reddy, BY ^{[1
]}

Kumar, GS ^{[1
]}

Iqbal, J ^{[1
]}

机构：

[1] Dr Reddys Res Fdn, Discovery Chem Synth, Hyderabad 500050, Andhra Pradesh, India

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 47期

关键词：

decarboxylation; alkylation; Friedel-Crafts reaction; rearrangement; Michael addition;

D O I：

10.1016/S0040-4039(01)01809-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A number of carbon substituents possessing various functional groups could be introduced onto aromatic nitro compounds using dimethyl malonate as a one-carbon source and linker. Decarboxylation of both the ester groups originating from dimethyl malonate in this methodology is particularly significant. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：8395 / 8398

页数：4

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