A structurally characterized azide-bridged dinuclear nickel(II) cryptate

被引：20

作者：

Fabbrizzi, L ^{[1
]}

Pallavicini, P ^{[1
]}

Parodi, L ^{[1
]}

Perotti, A ^{[1
]}

Sardone, N ^{[1
]}

Taglietti, A ^{[1
]}

机构：

[1] UNIV PAVIA,CTR GRANDI STRUMENTI,I-27100 PAVIA,ITALY

来源：

INORGANICA CHIMICA ACTA | 1996年 / 244卷 / 01期

关键词：

crystal structures; nickel complexes; azide-bridging complexes; cryptate complexes; dinuclear complexes;

D O I：

10.1016/0020-1693(96)04998-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The macrobicyclic ligand L2 forms dimetallic Ni-II cryptate species in a delimited pH range, which are further able to include one N-3-anion. The molecular structure of the azide-bridged complex shows an almost linear (NiNNNNiII)-N-II arrangement and a different coordination at the two metal sites (one Ni-II being octahedral, the other trigonal bipyramidal).

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页码：7 / 9

页数：3

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