Novel route to propylene carbonate: selective synthesis from propylene glycol and carbon dioxide

被引:71
作者
Tomishige, K [1 ]
Yasuda, H [1 ]
Yoshida, Y [1 ]
Nurunnabi, M [1 ]
Li, BT [1 ]
Kunimori, K [1 ]
机构
[1] Univ Tsukuba, Inst Mat Sci, Tsukuba, Ibaraki 3058573, Japan
关键词
propylene carbonate; CeO2-ZrO2 solid solution; propylene glycol; carbon dioxide;
D O I
10.1023/B:CATL.0000023720.39110.4e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
CeO2-ZrO2 solid solution catalysts are very effective for the selective synthesis of propylene carbonate (PC) from propylene glycol and carbon dioxide. Dipropylene glycols and poly ( PC) are expected to be formed as by-products, however, they were not detected at all in the analysis by gas chromatograph and FTIR.
引用
收藏
页码:45 / 49
页数:5
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