Organometallic molybdenum(V) complexes with primary phosphane ligands syntheses, spectroscopic properties, and crystal structures of [Cp'MoCl4(PH2R)] (R=2,4,6-(Pr3C6H2)-C-i, cyclohexyl, Cp'=C5H4Me)

被引：20

作者：

Felsberg, R

Blaurock, S

Jelonek, S

Gelbrich, T

Kirmse, R

Voigt, A

HeyHawkins, E

机构：

[1] Institut Für Anorganische Chemie, Universität, D-04103 Leipzig

来源：

CHEMISCHE BERICHTE-RECUEIL | 1997年 / 130卷 / 06期

关键词：

methylcyclopentadienyl molybdenum(V) tetrachloride; primary phosphane ligands; EPR spectroscopy; molybdenum;

D O I：

10.1002/cber.19971300621

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Cp'MoCl4(CH3CN)] (Cp' = C5H4Me) reacts with 2,4,6-triisopropylphenylphosphane or cyclohexylphosphane to give the phosphane complexes [Cp'MoCl4(PH2R)] [R = 2,4,6-(Pr3C6H2)-C-i (1), Cy (2)]. 1 and 2 were characterized spectroscopically (IR, MS) and by crystal structure determinations. EPR investigations in Liquid and frozen solution confirmed the presence of Mo(V) species and the data were used to analyze the spin-density distribution in the first coordination sphere.

引用

页码：807 / 812

页数：6

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