Kinetics and mechanism of the electrooxidation of formic acid - Spectroelectrochemical studies in a flow cell

被引：329

作者：

Chen, YX ^{[1
]}

Heinen, M ^{[1
]}

Jusys, Z ^{[1
]}

Behm, RJ ^{[1
]}

机构：

[1] Univ Ulm, Dept Surface Chem & Catalysis, D-89069 Ulm, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 06期

关键词：

electrochemistry; flow cell; IR spectroscopy; spectroelectrochemistry; time-resolved spectroscopy;

D O I：

10.1002/anie.200502172

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Go with the flow: A novel spectroelectrochemical flow cell with well-defined mass transport allows time-resolved electrochemical and in situ FTIR spectroscopy measurements under continuous electrolyte flow (e.g. during electrolyte exchange). Its potential for mechanistic and kinetic studies was demonstrated in studies on the electrooxidation of formic acid. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：981 / 985

页数：5

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