Combining in-situ organic modification of montmorillonite and the latex compounding method to prepare high-performance rubber-montmorillonite nanocomposites

被引:48
作者
Jia, QX
Wu, YP
Xu, YL
Mao, HH
Zhang, LQ [1 ]
机构
[1] Key Lab Beijing City Preparat & Proc Novel Polyme, Beijing 100029, Peoples R China
[2] Beijing Univ Chem Technol, Minist Educ, Key Lab Nanomat, Beijing 100029, Peoples R China
关键词
N-allyl-N; N-dimethyl-octadecylammonium chloride; clay; latex compounding method; nanocomposites; SBR;
D O I
10.1002/mame.200500376
中图分类号
T [工业技术];
学科分类号
08 [工学];
摘要
To improve the interfacial interaction in MMT-SBR nanocomposites, one type of UOAC was introduced to in-situ modified MMT before latex compounding with SBR. The influence of the UOAC/MMT ratio on the structure and properties of MMT/SBR nanocomposites were carefully studied by XRD, TEM, and mechanical testing. It was found that through the in-situ organic modification, a rubber-intercalated structure of MMT was obtained in the nanocomposites, and the amount of rubber-intercalated structure strongly depended on the UOAC/MMT ratio. The tensile strength of MMT-SBR nanocomposites was enhanced dramatically from 4 to 18 MPa by in-situ organic modification of MMT.
引用
收藏
页码:218 / 226
页数:9
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