Acyclic catena-diphosphinodiphosphonium dications [R3P-PR′-PR′-PR3]2+ or bisphosphine-diphosphenium complexes [R3P→PR′-PR′←PR3]2+:: Synthesis by reductive P-P coupling of [R3P-PR′Cl]+ and phosphine ligand exchange

被引：37

作者：

Dyker, C. Adam

Burford, Neil ^{[1
]}

Lumsden, Michael D.

Decken, Andreas

机构：

[1] Dalhousie Univ, Dept Chem, Halifax, NS B3H 4J3, Canada

[2] Dalhousie Univ, Atlantic Reg Magnet Resonance Ctr, Halifax, NS B3H 4J3, Canada

[3] Univ New Brunswick, Dept Chem, Fredericton, NB E3A 6E2, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 30期

关键词：

PHOSPHORUS; CHEMISTRY; PHOSPHANES; CATIONS; SALTS; CHAIN;

D O I：

10.1021/ja062972y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The acyclic tetraphosphorus dication [Ph3P-PPh-PPh-PPh3]2+ has been formed by the reductive coupling of [Ph3P-PPhCl]+, providing a new synthetic method for the systematic development of catena-phosphorus cations. Ligand exchange (Ph3P for Me3P) gives [Me3P-PPh-PPh-PMe3]2+, implicating these dications as bisphosphine-diphosphenium complexes. Copyright © 2006 American Chemical Society.

引用

收藏

页码：9632 / 9633

页数：2

相关论文

共 21 条

[1] THE PREPARATION AND REACTIONS OF 1,6-DIPHOSPHATRICYCLO[4.4.4.0]TETRADECANEDIIUM DITRIFLUOROMETHANESULFONATE [J].

ALDER, RW ;

GANTER, C ;

HARRIS, CJ ;

ORPEN, AG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (17) :1172-1174

[2] SYNTHESIS AND REACTIONS OF 1,6-DIPHOSPHABICYCLO[4.4.0]DECANE AND RELATED MOLECULES [J].

ALDER, RW ;

GANTER, C ;

HARRIS, CJ ;

ORPEN, AG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (17) :1170-1172

[3] Bridgehead diphosphines in the bicyclo[3.3.3]undecane and bicyclo[4.4.4]tetradecane series: synthesis, structure and properties [J].

Alder, RW ;

Ellis, DD ;

Gleiter, R ;

Harris, CJ ;

Lange, H ;

Orpen, AG ;

Read, D ;

Taylor, PN .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (10) :1657-1668

[4]

[Anonymous], CHEM COMMUN

[5] CONTRIBUTIONS TO THE CHEMISTRY OF PHOSPHORUS .118. CHAIN AND RING PHOSPHORUS-COMPOUNDS - ANALOGIES BETWEEN PHOSPHORUS AND CARBON-CHEMISTRY [J].

BAUDLER, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1982, 21 (07) :492-512

[6] CHEMISTRY OF PHOSPHORUS .218. MONOCYCLIC AND POLYCYCLIC PHOSPHANES [J].

BAUDLER, M ;

GLINKA, K .

CHEMICAL REVIEWS, 1993, 93 (04) :1623-1667

[7] OPEN-CHAIN POLYPHOSPHORUS HYDRIDES (PHOSPHANES) [J].

BAUDLER, M ;

GLINKA, K .

CHEMICAL REVIEWS, 1994, 94 (05) :1273-1297

[8] CONTRIBUTIONS TO THE CHEMISTRY OF PHOSPHORUS .178. POLYPHOSPHORUS COMPOUNDS - NEW RESULTS AND PERSPECTIVES [J].

BAUDLER, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (05) :419-441

[9] Small cyclopolyphosphinophosphonium cations:: Systematic development of fundamental catena-phosphorus frameworks [J].

Burford, N ;

Dyker, CA ;

Lumsden, M ;

Decken, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (38) :6196-6199

[10] Facile synthetic methods for the diversification of catena-polyphosphorus cations [J].

Burford, N ;

Dyker, CA ;

Decken, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (16) :2364-2367