Cerium(III) chloride and sodium octylthiopropionate as an effective inhibitor mixture for zinc corrosion in 0.5 M NaCl

It has been reported that cerium(III) chloride CeCl3 and sodium octylthiopropionate C8H17S(CH2)(2)COONa (NaOTP) are effective inhibitors for zinc corrosion in 0.5 M NaCl. In this study, synergistic inhibition of zinc corrosion in an aerated 0.5 M NaCl solution by a mixture of these inhibitors was investigated by polarization measurements after immersion of a zinc electrode in the solution for many hours. The inhibition efficiency of 1 x 10(-4) M CeCl3 plus 1 x 10(-5) M NaOTP mixture was high, 95.1% after both 3 and 120 h. X-ray photoelectron spectroscopy and electron-probe microanalysis for the inhibited electrode revealed that the zinc surface was covered with a protective film composed of an hydrated or hydroxylated Cc-rich oxide, a small amount of Zn(OH)(2) and a trace of Zn(OTP)(2) chelate. The inhibition effect of 1 x 10(-5) M NaOTP in the NaCl solution for the zinc electrode previously treated in 1 x 10(-3) M CeCl3 for 30 min in was also examined, indicating a higher inhibition efficiency, 96.3% after immersion of the electrode in the solution for 120 h. (C) 2002 Elsevier Science Ltd. All rights reserved.