Parallel solid-phase synthesis, screening, and encoding strategies for olefin-polymerization catalysts

被引：34

作者：

Boussie, TR ^{[1
]}

Murphy, V ^{[1
]}

Hall, KA ^{[1
]}

Coutard, C ^{[1
]}

Dales, C ^{[1
]}

Petro, M ^{[1
]}

Carlson, E ^{[1
]}

Turner, HW ^{[1
]}

Powers, TS ^{[1
]}

机构：

[1] Symyx Technol, Santa Clara, CA 95051 USA

来源：

TETRAHEDRON | 1999年 / 55卷 / 39期

关键词：

D O I：

10.1016/S0040-4020(99)00688-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A solid-phase protocol has been developed that allows for the parallel synthesis, screening, and chemical encoding of nickel (II) and palladium (II) olefin-polymerization catalysts. These catalysts display activity profiles comparable to the analogous homogeneous catalyst systems prepared by traditional methods. A chemical encoding strategy has also been developed which enables the chemical history of pooled solid-phase catalysts to be evaluated. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：11699 / 11710

页数：12

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