Bifunctional organometallic catalysts involving proton transfer or hydrogen bonding

被引：132

作者：

Grotjahn, DB ^{[1
]}

机构：

[1] San Diego State Univ, Dept Chem & Biochem, San Diego, CA 92182 USA

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2005年 / 11卷 / 24期

关键词：

cooperative effects; homogeneous catalysis; hydrogen bonds; P ligands; proton transfer;

D O I：

10.1002/chem.200500253

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Inspired by the cooperativity displayed by metalloenzymes, bifunctional organometallic complexes featuring pendant basic functional groups are designed and evaluated as catalysts in reactions for which enzymes are not suited. Anti-Markovnikov hydration of terminal alkynes is the focus, as are hydrogen bonding and proton transfer facilitated by the pendant groups.

引用

页码：7146 / 7153

页数：8

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