Hydrogenation of organic substrates by isocyanide polymer-bound Rh(PPh(3))(3)Cl

被引：18

作者：

Giannandrea, R

Mastrorilli, P

Zaccaria, G

Nobile, CF

机构：

[1] CTR STUDI CNR MISO,I-70126 BARI,ITALY

[2] POLITECN BARI,IST CHIM,I-70126 BARI,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1996年 / 109卷 / 02期

关键词：

hydrogenation; cross-linked polymer; isocyanide polymer; supported catalyst; rhodium;

D O I：

10.1016/1381-1169(96)00005-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rh(PPh(3))(3)Cl undergoes easy and quantitative coordination to hydrophilic macromolecular isocyanides to give a supported rhodium complex which, activated at 50 degrees C under 1 atm dihydrogen behaves as a versatile and recyclable catalyst for the hydrogenation of alkenes, alkynes, nitriles and nitrocompounds under mild conditions. Unsaturated aldehydes are converted into saturated aldehydes whereas nitriles are selectively converted into the corresponding imines or secondary amines depending on the reaction conditions.

引用

页码：113 / 117

页数：5

共 7 条

[1] PREPARATION OF ISOCYANO POLYMER SUPPORTS AND THEIR COMPLEXES WITH CATALYTICALLY RELEVANT TRANSITION-METAL CENTERS [J].

ARSHADY, R ;

BASATO, M ;

CORAIN, B ;

RONCATO, M ;

ZECCA, M ;

DELLAGIUSTINA, L ;

LORA, S ;

PALMA, G .

JOURNAL OF MOLECULAR CATALYSIS, 1989, 53 (01) :111-128

[2] DIRECT SYNTHESIS OF ALCOHOLS FROM N-OLEFINS AND SYNGAS IN THE LIQUID-PHASE CATALYZED BY RHODIUM SUPPORTED ON CROSS-LINKED ACRYLIC RESINS [J].

CORAIN, B ;

BASATO, M ;

ZECCA, M ;

BRACA, G ;

GALLETTI, AMR ;

LORA, S ;

PALMA, G ;

GUGLIELMINOTTI, E .

JOURNAL OF MOLECULAR CATALYSIS, 1992, 73 (01) :23-41

[3]

Gassman P. G., 1969, ORG SYNTH, V49, P1, DOI DOI 10.15227/ORGSYN.049.0001

[4]

James B. R., 1982, COMPREHENSIVE ORGANO, V8, P285

[5] CATALYTIC ACTIVITY OF PD(ACO)2 COORDINATED TO CROSS-LINKED POLYMERIC ISOCYANIDES [J].

KEIM, W ;

MASTRORILLI, P ;

NOBILE, CF ;

RAVASIO, N ;

CORAIN, B ;

ZECCA, M .

JOURNAL OF MOLECULAR CATALYSIS, 1993, 81 (02) :167-184

[6] REGIOSELECTIVE HYDROGENATION OF 3-PHENYLPROPENAL AND OF TRANS-2-HEXENAL TO SATURATED ALDEHYDES CATALYZED BY ULTRAFINE RHODIUM PARTICLES DISPERSED ON ACRYLIC RESINS [J].

MASTRORILLI, P ;

NOBILE, CF ;

RAVASIO, N ;

CORAIN, B ;

ZECCA, M .

JOURNAL OF MOLECULAR CATALYSIS, 1993, 80 (02) :L5-L8

[7] ACTIVE STATES OF RHODIUM IN RHODIUM EXCHANGED Y-ZEOLITE CATALYSTS FOR HYDROGENATION OF ETHYLENE AND ACETYLENE AND DIMERIZATION OF ETHYLENE STUDIED WITH X-RAY PHOTOELECTRON-SPECTROSCOPY [J].

OKAMOTO, Y ;

ISHIDA, N ;

IMANAKA, T ;

TERANISHI, S .

JOURNAL OF CATALYSIS, 1979, 58 (01) :82-94

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