A synthesis, MAS NMR, synchrotron X-ray powder diffraction, and computational study of zeolite SSZ-23

被引：36

作者：

Camblor, MA

Díaz-Cabañas, MJ

Cox, PA

Shannon, IJ

Wright, PA

Morris, RE

机构：

[1] Univ Politecn Valencia, Inst Tecnol Quim, E-46071 Valencia, Spain

[2] Univ Portsmouth, Sch Pharm & Biomed Sci, Portsmouth PO1 2DT, Hants, England

[3] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

CHEMISTRY OF MATERIALS | 1999年 / 11卷 / 10期

关键词：

D O I：

10.1021/cm991057r

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The zeolite SSZ-23 (STT) is the first zeolite found to contain channels bounded by seven and nine tetrahedral atom windows. A survey of the synthetic conditions needed to prepare SSZ-23 has been carried out, and the resulting materials characterized by synchrotron X-ray powder diffraction and magic-angle spinning NMR spectroscopy to obtain details of the long-range crystalline structure and short-range connectivity defects. The lattice energy minimized structure is in excellent agreement with the experimental results, and a comparison with other zeolites that have been simulated in this way is made.

引用

页码：2878 / 2885

页数：8

共 25 条

[1] Synthesis in fluoride and hydroxide media and structure of the extra-large pore pure silica zeolite CIT-5 [J].