An ice phase of lowest thermal conductivity

被引:13
作者
Andersson, O [1 ]
Johari, GP
Suga, H
机构
[1] Umea Univ, Dept Phys, S-90187 Umea, Sweden
[2] McMaster Univ, Dept Mat Sci & Engn, Hamilton, ON L8S 4L7, Canada
[3] Solid State Lab, Osaka 5620001, Japan
关键词
D O I
10.1063/1.1703523
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
On pressurizing at temperatures near 130 K, hexagonal and cubic ices transform implosively at 0.8-1 GPa. The phase produced on transformation has the lowest thermal conductivity among the known crystalline ices and its value decreases on increase in temperature. An ice phase of similar thermal conductivity is produced also when high-density amorphous ice kept at 1 GPa transforms on slow heating when the temperature reaches similar to155 K. These unusual formation conditions, the density and its distinguished thermal conductivity, all indicate that a distinct crystal phase of ice has been produced. (C) 2004 American Institute of Physics.
引用
收藏
页码:9612 / 9617
页数:6
相关论文
共 28 条
[1]   Thermal conductivity of amorphous ices [J].
Andersson, O ;
Suga, H .
PHYSICAL REVIEW B, 2002, 65 (14) :1-4
[2]   THERMAL-CONDUCTIVITY OF THE IH AND XI PHASES OF ICE [J].
ANDERSSON, O ;
SUGA, H .
PHYSICAL REVIEW B, 1994, 50 (10) :6583-6588
[3]   STRUCTURE OF HIGH-DENSITY AMORPHOUS WATER .1. X-RAY-DIFFRACTION STUDY [J].
BIZID, A ;
BOSIO, L ;
DEFRAIN, A ;
OUMEZZINE, M .
JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (04) :2225-2230
[4]   X-RAY STUDY OF HIGH-DENSITY AMORPHOUS WATER [J].
BOSIO, L ;
JOHARI, GP ;
TEIXEIRA, J .
PHYSICAL REVIEW LETTERS, 1986, 56 (05) :460-463
[5]   Supercooled and glassy water [J].
Debenedetti, PG .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2003, 15 (45) :R1669-R1726
[6]   WATER ICE POLYMORPHS AND THEIR SIGNIFICANCE ON PLANETARY SURFACES [J].
GAFFNEY, ES ;
MATSON, DL .
ICARUS, 1980, 44 (02) :511-519
[7]   Potential-energy landscape study of the amorphous-amorphous transformation in H2O -: art. no. 115504 [J].
Giovambattista, N ;
Stanley, HE ;
Sciortino, F .
PHYSICAL REVIEW LETTERS, 2003, 91 (11)
[8]   Polyamorphism in low temperature water: A simulation study [J].
Guillot, B ;
Guissani, Y .
JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (22) :11740-11752
[9]   Direct structural measurements of relaxation processes during transformations in amorphous ice [J].
Guthrie, M ;
Urquidi, J ;
Tulk, CA ;
Benmore, CJ ;
Klug, DD ;
Neuefeind, J .
PHYSICAL REVIEW B, 2003, 68 (18)
[10]   An estimate for the Gibbs energy of amorphous solid waters and differences between the low-density amorph and glassy water [J].
Johari, GP .
JOURNAL OF CHEMICAL PHYSICS, 2000, 112 (19) :8573-8580