Preparation and electrorheological properties of triethanolamine-modified TiO2

被引:58
作者
Cao, J. G. [1 ]
Shen, M. [1 ]
Zhou, L. W. [1 ]
机构
[1] Fudan Univ, Dept Phys, State Key Lab Appl Surface Phys, Shanghai 200433, Peoples R China
基金
中国国家自然科学基金;
关键词
electrorheological fluids; molecular dipole moment;
D O I
10.1016/j.jssc.2006.01.078
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The high molecular dielectric dipole moment of doping material is promising, to improve the electrorholegical (ER) effect. It is found that triethanolamine (the molecular dipole moment of triethanolamine is 3,48)-modified TiO2 has good ER properties. Under 5 kV/mm external electric field. the yield stress is 32.6 kPa, which is about 50 times higher than that of TiO2 and the leaking electric current density is lower than 16 mu A/cm(3). The sedimentation rate is about 98% in 20 days. (C), 2006 Elsevier Inc. All rights reserved.
引用
收藏
页码:1565 / 1568
页数:4
相关论文
共 17 条
[1]  
BLOCK H, 1995, PROGRESS IN ELECTRORHEOLOGY, P19
[2]   ELECTRORHEOLOGICAL FLUIDS [J].
HALSEY, TC .
SCIENCE, 1992, 258 (5083) :761-766
[3]  
Hao T, 2001, ADV MATER, V13, P1847, DOI 10.1002/1521-4095(200112)13:24<1847::AID-ADMA1847>3.0.CO
[4]  
2-A
[5]   Mechanism of the electrorheological effect: Evidence from the conductive, dielectric, and surface characteristics of water-free electrorheological fluids [J].
Hao, T ;
Kawai, A ;
Ikazaki, F .
LANGMUIR, 1998, 14 (05) :1256-1262
[6]   Electrorheology of miscible blended liquid crystalline polymer: A dielectric property approach [J].
Kawai, A ;
Ide, Y ;
Inoue, A ;
Ikazaki, F .
JOURNAL OF CHEMICAL PHYSICS, 1998, 109 (11) :4587-4591
[7]  
Kawano Y., 1998, CVD PREV, V1, P336
[8]   FREQUENCY-DEPENDENCE OF ELECTRORHEOLOGICAL FLUIDS IN AN AC ELECTRIC-FIELD [J].
LU, KQ ;
WEN, WJ ;
LI, CX ;
XIE, SS .
PHYSICAL REVIEW E, 1995, 52 (06) :6329-6332
[9]   Particle size scaling of the giant electrorheological effect [J].
Wen, WJ ;
Huang, XX ;
Sheng, P .
APPLIED PHYSICS LETTERS, 2004, 85 (02) :299-301
[10]   The giant electrorheological effect in suspensions of nanoparticles [J].
Wen, WJ ;
Huang, XX ;
Yang, SH ;
Lu, KQ ;
Sheng, P .
NATURE MATERIALS, 2003, 2 (11) :727-730