Membrane- and surface-grafted polymers and proteins in shear flows: Chain mobility and transport coefficients

被引：3

作者：

Bright, JN ^{[1
]}

Williams, DRM ^{[1
]}

机构：

[1] Australian Natl Univ, Res Sch Phys Sci & Engn, Dept Math Appl, Canberra, ACT 0200, Australia

来源：

LANGMUIR | 1999年 / 15卷 / 11期

关键词：

D O I：

10.1021/la9803880

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We consider the problem of a mobile polymer chain anchored to a surface in the presence of a shear flow. We examine the case where the surface is solid, where it is the interface between two liquids, and where it is a membrane. Rodlike polymers and flexible polymers under good and theta conditions are studied. We find that at low shear rates the chain speed increases linearly with the shear rate. At higher shear rates a nonlinear relation is usually obtained due to chain distortion.

引用

页码：3836 / 3844

页数：9

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