A new modification of NaCoPO4 with the zeolite ABW structure

被引：33

作者：

Chippindale, AM

Cowley, AR

Chen, JS

Gao, QM

Xu, RR

机构：

[1] Chem Crystallog Lab, Oxford OX1 3PD, England

[2] Jilin Univ, Dept Chem, Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S010827019900414X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, sodium cobalt(II) phosphate, a new polymorph of NaCoPO4, crystallizes as a monoclinic modification of the zeolite ABW structure. The five-coordinate Na+ cations reside within channels running through an open cobalt-phosphate framework constructed from four-, six- and eight-membered rings of alternating CoO4 and PO4 tetrahedra. The channels are enclosed by the eight-membered rings.

引用

页码：845 / 847

页数：3

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