B-N compounds for chemical hydrogen storage

被引：950

作者：

Hamilton, Charles W. ^{[2
]}

Baker, R. Tom ^{[1
]}

Staubitz, Anne ^{[3
]}

Manners, Ian ^{[3
]}

机构：

[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

[2] Los Alamos Natl Lab, Los Alamos, NM 87545 USA

[3] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

METAL-ORGANIC FRAMEWORKS; AMINE-BORANE ADDUCTS; CERAMIC CONVERSION REACTIONS; YIELD POLYMERIC PRECURSOR; INITIO DIRECT DYNAMICS; BORON-NITROGEN BONDS; MAIN-GROUP ELEMENTS; AMMONIA-BORANE; THERMAL-DECOMPOSITION; CATALYZED DEHYDROGENATION;

D O I：

10.1039/b800312m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogen storage for transportation applications requires high volumetric and gravimetric storage capacity. B-N compounds are well suited as storage materials due to their light weight and propensity for bearing multiple protic (N-H) and hydridic (B-H) hydrogens. This critical review briefly covers the various methods of hydrogen storage, and then concentrates on chemical hydrogen storage using B-N compounds. The simplest B-N compound, ammonia borane (H(3)NBH(3)), which has a potential 19.6 wt% hydrogen storage capacity, will be emphasised (127 references).

引用

页码：279 / 293

页数：15

共 172 条

[11] Amineborane-based chemical hydrogen storage: Enhanced ammonia borane dehydrogenation in ionic liquids [J].