Formation mechanism of a multihollow structure within submicron-sized styrene/methacrylic acid copolymer particles by the stepwise acid/alkali method

被引：21

作者：

Okubo, M ^{[1
]}

Sakauchi, A ^{[1
]}

Okada, M ^{[1
]}

机构：

[1] Kobe Univ, Fac Engn, Dept Sci & Chem Engn, Kobe, Hyogo 6578501, Japan

来源：

COLLOID AND POLYMER SCIENCE | 2002年 / 280卷 / 04期

关键词：

interfacial free energy; multihollow; emulsion polymerization; stepwise alkali/acid method; swelling;

D O I：

10.1007/s003960100551

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The formation mechanism of a multihollow structure within submicron-sized styrene/methacrylic acid copolymer particles by the stepwise alkali/acid method, which we proposed in 1990, was discussed thermodynamically from the viewpoint of interfacial free energy.

引用

页码：303 / 309

页数：7

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