Synthesis, crystal and molecular structure of [Sn(η4-P2C2But2)]:: the first non transition metal 1,3-diphosphacyclobutadienyl compound

被引：25

作者：

Francis, MD ^{[1
]}

Hitchcock, PB ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 01期

关键词：

D O I：

10.1039/b110228c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of [Zr(eta(5)-C5H5)(2)(PCBut)(2)] with SnCl2 led to the novel monomeric (1,3-diphosphacyclobutadienyl)tin(II) half sandwich complex [Sn(eta(4)-P2C2Bu2t)] which has been characterised by multinuclear NMR spectroscopy and in the solid state by a single crystal X-ray diffraction study.

引用

页码：86 / 87

页数：2

共 15 条

[1]

BINGER P, 1991, ANGEW CHEM INT EDIT, V30, P207

[2] PHOSPHORUS-COMPOUNDS OF UNUSUAL COORDINATION .11. 1,3-DIPHOSPHACYCLOBUTADIENECOBALT(I) COMPLEXES FROM PHOSPHAALKYNES [J].

BINGER, P ;

MILCZAREK, R ;

MYNOTT, R ;

REGITZ, M ;

ROSCH, W .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (07) :644-645

[3] LAMBDA-3-1,3-DIPHOSPHACYCLOBUTADIENE-COBALT COMPLEXES BY CYCLO-DIMERIZATION OF LAMBDA-3-PHOSPHAALKYNES [J].

BINGER, P ;

MILCZAREK, R ;

MYNOTT, R ;

KRUGER, C ;

TSAY, YH ;

RAABE, E ;

REGITZ, M .

CHEMISCHE BERICHTE-RECUEIL, 1988, 121 (04) :637-645

[4] (eta(8)-cyclooctatetraene)(eta(4)-1,2- and -1,3-diphosphacyclobutadiene)titanium: Preparation, structure, and reactivity [J].

Binger, P ;

Glaser, G ;

Albus, S ;

Kruger, C .

CHEMISCHE BERICHTE-RECUEIL, 1995, 128 (12) :1261-1265

[5] BIS(METHYLCYCLOPENTADIENYL) DERIVATIVES OF GERMANIUM(II), TIN(II), AND LEAD(II) - H-1 AND C-13 NMR PROPERTIES AND COMPARISON WITH THOSE FOR ANALOGS FORMED BY UNIVALENT METALS (LI, K, AND TL) [J].

BONNY, A ;

MCMASTER, AD ;

STOBART, SR .

INORGANIC CHEMISTRY, 1978, 17 (04) :935-938

[6] SYNTHESIS AND MOLECULAR-STRUCTURE OF TRIS(ETA(4)-2,4-DI-TERT-BUTYL-1,3-DIPHOSPHACYCLOBUTADIENE)MOLYBDENUM(0) [J].

CLOKE, FGN ;

FLOWER, KR ;

HITCHCOCK, PB ;

NIXON, JF .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (04) :489-490

[7]

DILLON KB, 1998, PHOSPHORUS CARBON CO, P258

[8]

DREISS M, 1987, J ORGANOMET CHEM, V334, pC35

[9]

HICHCOCK PB, 1986, J CHEM SOC CHEM COMM, P737

[10] A THEORETICAL-STUDY OF THE DIMERIZATION OF PHOSPHAETHYNE (HCP) - HEAD-TO-TAIL VERSUS HEAD-TO-HEAD CYCLOADDITION [J].

NGUYEN, MT ;

LANDUYT, L ;

VANQUICKENBORNE, LG .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (10) :2817-2821

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