Inclusion complexes of multiarm poly(ethylene glycol) with cyclodextrins

被引:59
作者
Jiao, H [1 ]
Goh, SH [1 ]
Valiyaveettil, S [1 ]
机构
[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
关键词
D O I
10.1021/ma0118163
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Stoichiometric crystalline inclusion complexes with α-CD and γ-CD were formed from star-shaped PEG with 3, 4, or 6 arms. A stoichiometry (ethylene glycol unit:CD) of ca. 2:1 for α-CD/multiarm PEG and ca. 4:1 for γ-CD/multiarm PEG was established by 1H NMR measurements. XRD measurements revealed that all the complexes possess a column structure.
引用
收藏
页码:1980 / 1983
页数:4
相关论文
共 32 条
[1]  
Bender M.L., 1978, Cyclodextrin Chemistry
[2]  
Fujita H, 1999, MACROMOL CHEM PHYSIC, V200, P706, DOI 10.1002/(SICI)1521-3935(19990401)200:4<706::AID-MACP706>3.0.CO
[3]  
2-2
[4]   Complex formation between poly(oxytrimethylene) and cyclodextrins [J].
Harada, A ;
Okada, M ;
Kamachi, M .
ACTA POLYMERICA, 1995, 46 (06) :453-457
[5]   Preparation and characterization of inclusion complexes of polyisobutylene with cyclodextrins [J].
Harada, A ;
Suzuki, S ;
Okada, M ;
Kamachi, M .
MACROMOLECULES, 1996, 29 (17) :5611-5614
[6]   PREPARATION AND PROPERTIES OF INCLUSION COMPLEXES OF POLY(ETHYLENE GLYCOL) WITH ALPHA-CYCLODEXTRIN [J].
HARADA, A ;
LI, J ;
KAMACHI, M .
MACROMOLECULES, 1993, 26 (21) :5698-5703
[7]   COMPLEX-FORMATION BETWEEN POLY(ETHYLENE GLYCOL) AND ALPHA-CYCLODEXTRIN [J].
HARADA, A ;
KAMACHI, M .
MACROMOLECULES, 1990, 23 (10) :2821-2823
[8]   Preparation and characterization of inclusion complexes of aliphatic polyesters with cyclodextrins [J].
Harada, A ;
Nishiyama, T ;
Kawaguchi, Y ;
Okada, M ;
Kamachi, M .
MACROMOLECULES, 1997, 30 (23) :7115-7118
[9]   Complex formation of poly(epsilon-caprolactone) with cyclodextrin [J].
Harada, A ;
Kawaguchi, Y ;
Nishiyama, T ;
Kamachi, M .
MACROMOLECULAR RAPID COMMUNICATIONS, 1997, 18 (07) :535-539
[10]   Preparation and structures of supramolecules between cyclodextrins and polymers [J].
Harada, A .
COORDINATION CHEMISTRY REVIEWS, 1996, 148 :115-133