Retention of optical purity in H-D exchange reactions catalysed by cobalt-aluminium alloy in Na2CO3-D2O

被引：4

作者：

Mukumoto, M

Tsuzuki, H

Mataka, S

Tashiro, M

Tsukinoki, T

Nagano, Y

机构：

[1] KYUSHU UNIV, GRAD SCH ENGN SCI, DEPT MOLEC SCI & TECHNOL, KASUGA, FUKUOKA 816, JAPAN

[2] KYUSHU UNIV, CTR ADV INSTRUMENTAL ANAL, KASUGA, FUKUOKA 816, JAPAN

[3] KYUSHU UNIV, INST ADV MAT STUDY, KASUGA, FUKUOKA 816, JAPAN

[4] TOHWA UNIV, TOHWA INST SCI, MINAMI KU, FUKUOKA 815, JAPAN

来源：

CHEMISTRY LETTERS | 1996年 / 02期

关键词：

D O I：

10.1246/cl.1996.165

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Co-Al alloy in a sodium carbonate-deuterium oxide solution catalyzes the H-D exchange reaction of optically active benzylic hydrogen atom without racemization.

引用

页码：165 / 166

页数：2

共 16 条

[1] ULTRASONICALLY INDUCED ENHANCEMENT OF ISOTOPE-EXCHANGE CATALYSTS - SURFACE-ANALYSIS OF RANEY-NICKEL ALLOYS [J].

CIOFFI, EA ;

WILLIS, WS ;

SUIB, SL .

LANGMUIR, 1988, 4 (03) :697-702

[2] CATALYTIC DEUTERIUM-EXCHANGE REACTIONS WITH ORGANICS .70. DEUTERATION OF ALKYL HYDROGENS IN SHORT-CHAIN ALKYLBENZENES USING HOMOGENEOUS PLATINUM AND HETEROGENEOUS PLATINUM AND NICKEL CATALYSTS [J].

GARNETT, JL ;

KENYON, RS .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1974, 27 (05) :1023-1032

[3]

GARNETT JL, 1971, CATALY REV, V5, P229

[4] ELECTROPHILIC SUBSTITUTION AT SATURATED CARBON .48. HIGH STEREOSPECIFICITY IN A TRANSAMINATION REACTION [J].

GUTHRIE, RD ;

JAEGER, DA ;

MEISTER, W ;

CRAM, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (20) :5137-&

[5]

HARTUNG WH, 1953, ORG REACTIONS, V7, P263

[6] REDUCTION OF AZABICYCLIC KETONES [J].

HOUSE, HO ;

MULLER, HC ;

PITT, CG ;

WICKHAM, PP .

JOURNAL OF ORGANIC CHEMISTRY, 1963, 28 (09) :2407-&

[7] NICKEL-ALUMINUM ALLOY AS A REDUCING AGENT [J].

KEEFER, LK ;

LUNN, G .

CHEMICAL REVIEWS, 1989, 89 (03) :459-502

[8]

MAEDA M, 1977, CHEM PHARM BULL, V25, P3329

[9]

MITSUI S, 1970, SESSYOKU KANGEN HANN, P14

[10]

MUKUMOTO M, 1995, J DEUTERIUM SCI, V4, P85

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