pH dependence of inclusion complexation between cationic poly(ε-lysine) and α-cyclodextrin

被引:65
作者
Huh, KM [1 ]
Tomita, H [1 ]
Ooya, T [1 ]
Lee, WK [1 ]
Sasaki, S [1 ]
Yui, N [1 ]
机构
[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Ishikawa 9231292, Japan
关键词
D O I
10.1021/ma012003h
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 [高分子化学与物理]; 080501 [材料物理与化学]; 081704 [应用化学];
摘要
The inclusion complexation (IC) of between cationic poly(ε-lysine) (PL) chains and α-cyclodextrin (CD) molecules under varied conditions was reported. It was found that the ionization of the side groups control the threading of CD molecules. The analysis showed that the yield of PL ICs was significantly affected by the pH of aqueous media, due to the protonation of amino side groups of PL and the ionization of hydroxyl groups of α-CD.
引用
收藏
页码:3775 / 3777
页数:3
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