Hydrogenation properties of complex alkali metal hydrides fabricated by mechano-chemical synthesis

被引：146

作者：

Zaluski, L

Zaluska, A

Ström-Olsen, JO

机构：

[1] McGill Univ, Ctr Phys Mat, Montreal, PQ H3A 2T8, Canada

[2] McGill Univ, Dept Phys, Montreal, PQ H3A 2T8, Canada

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1999年 / 290卷 / 1-2期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0925-8388(99)00211-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mechano-chemical synthesis was used to produce complex alkali metal hydrides. Various complex hydrides have been synthesized, for example Li3AlH6, Na3AlH6, (Li-Na)(3)AlH6, (Li-Na-B)(3)AlH6. Complex alkali metal hydrides fabricated by mechano-chemical processes exhibit very good reactivity in hydriding/dehydriding reactions. They have excellent cyclability and cover a wide range of operational temperatures and pressures. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：71 / 78

页数：8

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