Analysis of flavonoid constituents from leaves of Acanthopanax senticosus Harms by electrospray tandem mass spectrometry

被引:54
作者
Chen, ML [1 ]
Song, FR [1 ]
Guo, MQ [1 ]
Liu, ZQ [1 ]
Liu, SY [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
关键词
D O I
10.1002/rcm.574
中图分类号
Q5 [生物化学];
学科分类号
071010 [生物化学与分子生物学]; 081704 [应用化学];
摘要
Three known flavonoids, quercetin, quercitrin (quercetin-3-0-rhamnoside) and rutin (quercetin-3-0-rutinoside), have been identified for the first time in the leaves of Acanthopanax senticosus Harms by using electrospray tandem mass spectrometry techniques (ESI-MSn). The flavonoid hyperin (quercetin-3-0-beta-galactoside), already known to be present, was also investigated. The diagnostic fragment ions of the aglycone quercetin were obtained in the ESI-MSn experiments, and a fragmentation mechanism proposed. Copyright (C) 2002 John Wiley Sons, Ltd.
引用
收藏
页码:264 / 271
页数:8
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