Structural characterization of a photoinduced molecular switch

被引：155

作者：

Marchivie, M

Guionneau, P

Howard, JAK

Chastanet, G

Létard, JF

Goeta, AE

Chasseau, D

机构：

[1] ICMCB, Grp Sci Mol, UPR 9048, F-33608 Pessac, France

[2] Univ Durham, Dept Chem, Chem Crystallog Grp, Durham DH1 3LE, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 02期

关键词：

D O I：

10.1021/ja016980k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structures in both irradiated and nonirradiated states of a photoinduced molecular switch based on the spin-crossover phenomenon are presented. From the structural point of view, the light-induced metastable high-spin state of the spin-crossover complex [Fe(phen)2(NCS)2] (phen = 1,10-phenanthroline) shows significant differences with the low-spin state but also with the thermally induced high-spin state. Copyright © 2002 American Chemical Society.

引用

页码：194 / 195

页数：2

共 21 条

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[Anonymous], 1998, PROGRAMS CRYSTAL STR

[2]

*BRUK AN XRAY INST, 1998, SAINT VERS 5 0

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