Electrochemical synthesis of tetrakis [N-methylbenzothiazole-2(3H)-selone]selenium(2+)tetrafluoroborate: An uncommon dication containing the mixed-valence Se-5 framework

被引：3

作者：

Adamo, C

Demartin, F

Deplano, P

Devillanova, FA

Isaia, F

Lelj, F

Lippolis, V

Lukes, P

Mercuri, ML

机构：

[1] UNIV CAGLIARI, DIPARTIMENTO CHIM & TECNOL INORGAN & MET ORGAN, I-09124 CAGLIARI, ITALY

[2] UNIV BASILICATA, DIPARTIMENTO CHIM, I-85100 POTENZA, ITALY

[3] UNIV MILAN, DIPARTIMENTO CHIM STRUCT & STEREOCHIM INORGAN, I-20133 MILAN, ITALY

[4] UNIV MILAN, CTR CNR, I-20133 MILAN, ITALY

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 07期

关键词：

D O I：

10.1039/cc9960000873

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemical oxidation of N-methylbenzothiazole-2(3H)-selone leads to tetrakis[N-methylbenzothiazole-2(3H-selone]selenium(2+) tetrafluoroborate showing an uncommon dication containing a non-cyclic square-planar Se-5 framework; both Mulliken and NBO population analyses explain the relatively long Se-Se bond lengths between the central and the peripheral selenium atoms.

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收藏

页码：873 / 874

页数：2

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