Is the 'Azores Hotspot' a Wetspot? Insights from the Geochemistry of Fluid and Melt Inclusions in Olivine of Pico Basalts

The concept of an 'Azores mantle plume' has been widely debated, and the existence of an Azores hotspot questioned. In an effort to shed new light on this controversy, we present He isotope and major, trace and volatile element compositions for basaltic scoriae from five monogenetic cones emplaced along the fissure zone of Pico Island, the youngest island of the Azores archipelago. The bulk scoriae and lavas are moderately alkaline basalts, and their He isotope ratios, determined on olivine crystals, vary between 10 center dot 2 and 11 center dot 1 +/- 0 center dot 1 R-a. In contrast, melt inclusions hosted in olivine (Fo(76-83 center dot 5)) span a large range of compositions (K2O = 0 center dot 7-1 center dot 7 wt %; Ce = 32-65 ppm; Nb = 21-94 ppm), which extends the compositional field of lavas erupted along the Pico fissure zone. This chemical evolution is predominantly controlled by polybaric fractional crystallization. Most melt inclusions share similar enrichments in large ion lithophile and light rare earth elements, and trace element ratios (La/Sm, La/Yb, Sr/Nd, Ta/Th, Zr/Y) with their bulk-rocks. Only a few of them differ in their lower contents of incompatible elements and La/Sm, Li/Ta and Na/K ratios, a feature that is ascribed to distinct conditions of melting. As a whole, the melt inclusions preserve high and variable volatile contents, and contain up to 1 center dot 8-2 center dot 0 wt % of H2O and 0 center dot 4 wt % of CO2. The total fluid pressures, retrieved from the dissolved CO2 and H2O concentrations, and the P-CO2 from fluid inclusions, indicate magma ponding and crystallization at the crust-mantle boundary (ca. 18 km deep). The H2O/Cl and H2O/Ce ratios in the inferred parental undegassed basalts of the Pico fissure zone average 0 center dot 036 +/- 0 center dot 006 and 259 +/- 21, respectively. The latter value is significantly higher than that reported for typical mid-ocean ridge basalts from the southern Mid-Atlantic Ridge, but is similar to published ratios for submarine undegassed basalts from the Azores platform. Combining the calculated compositions of Pico primary magmas formed by low degrees of melting with recent geophysical data for the Azores, we propose a model for Azores magma generation involving the decompression melting of a water-enriched mantle domain (H2O = 680-570 ppm) with an estimated temperature excess of 120 degrees C with respect to the Mid-Atlantic Ridge.