Temperature dependence of the probability of chain growth for hydrocarbon formation by electrochemical reduction of CO2

被引：10

作者：

Ougitani, Y ^{[1
]}

Aizawa, T ^{[1
]}

Sonoyama, N ^{[1
]}

Sakata, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2001年 / 74卷 / 11期

关键词：

D O I：

10.1246/bcsj.74.2119

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The temperature dependence of the probability of chain growth was studied for hydrocarbons formed at Fe and Ni electrodes by electrochemical CO2 reduction. The faradaic efficiency for hydrocarbons increased with increasing temperature. The distribution of the produced hydrocarbons followed well the Schultz Flory equation. The probability of chain growth increased with increasing temperature. Based on the temperature dependence of the probability of chain growth, the mechanism of the electrochemical Fischer Tropsch reaction is discussed.

引用

页码：2119 / 2122

页数：4

共 8 条

[1]

Anderson R.B., 1978, J CATAL, V55, P14

[2] ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE ON VARIOUS METAL-ELECTRODES IN LOW-TEMPERATURE AQUEOUS KHCO3 MEDIA [J].