Stereocontrolled conversion of secondary benzyl ether tricarbonylchromium(0) complexes into tertiary benzyl ether complexes

被引：18

作者：

Gibson, SE

Potter, PCV

Smith, MH

机构：

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 24期

关键词：

D O I：

10.1039/cc9960002757

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Deprotonation of enantiomerically enriched secondary benzyl ether tricarbonylchromium(0) complexes (96-99% ee) with tert-butyllithium followed by quenching with a range of electrophiles gives tertiary benzyl ether tricarbonylchromium(0) complexes of high enantiomeric purity (92-98.5% ee) in good yield (65-94%) with overall retention of configuration.

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页码：2757 / 2758

页数：2

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