Are feldspar-to-mica reactions necessarily reaction-softening processes in fault zones?

Reaction-softening by mineralogical changes from feldspars to sericite has been documented from many fault zones. During external crystalline basement deformation in the Alpine orogeny, the Ser Barbier thrust and splay faults in the Pelvoux Massif experienced ultracataclasis and sericitisation. Microstructural information and geochemical data from the fault rocks suggest that different muscovitisation reactions occurred at different times within the evolution of the fault zone, and each reaction had its own impact on fault rheology. Early cataclasis aided chemical breakdown of orthoclase feldspars to muscovite, yet quartz release accompanying this process resulted in local cementation and consequent hardening of the ultracataclasite. Continued deformation was accompanied by muscovitisation of the albite feldspar, and resulted in the formation of mica-rich fault rocks which experienced progressive silica removal by the fluid with increasing deformation. At this stage, reaction-enhanced ductility dominated. Much of the early cemented ultracataclasites escaped later deformation, and their low permeability allowed preservation of their early geochemical characteristics by preventing later fluid access. Such findings demonstrate how the complex interplay between deformation processes and geochemical reactions may result in a changing rheology during fault zone evolution. (C) 1999 Elsevier Science Ltd. All rights reserved.