Synthesis and characterization of new binuclear Co(0) complexes with diphosphinoamine ligands. A potential approach for asymmetric Pauson-Khand reactions

被引:58
作者
Gimbert, Y [1 ]
Robert, F [1 ]
Durif, A [1 ]
Averbuch, MT [1 ]
Kann, N [1 ]
Greene, AE [1 ]
机构
[1] Univ Grenoble 1, Chim Rech & Serv Cristallog, LEDSS, F-38041 Grenoble, France
关键词
D O I
10.1021/jo982245o
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis bf P-N-P bidentate ligands and the evaluation, based on IR and X-ray data, of their pi-acceptor properties in the complexes a derived from phenylacetylene-dicobalt hexacarbonyl have been carried out. In addition, the reactivity of these complexes in the Pauson-Khand reaction has been examined.
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页码:3492 / 3497
页数:6
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