Molecular versus supramolecular chemistry: The rotational barriers about covalent bonds and hydrogen bonds

被引：8

作者：

Alkorta, I ^{[1
]}

Elguero, J ^{[1
]}

机构：

[1] CSIC, Inst Quim Med, E-28006 Madrid, Spain

来源：

STRUCTURAL CHEMISTRY | 2002年 / 13卷 / 01期

关键词：

1,1,1-trifluoroethane; ethylene; hydrogen bonds; trifluoromethane/ammonia dimer; water dimer;

D O I：

10.1023/A:1013429532324

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The barrier about the C-C bond in 1,1,1-trifluoroethane amounts to 13-14 U mol(-1) while that about the hydrogen bond in the trifluoromethane/ammonia complex is almost null.

引用

页码：97 / 98

页数：2

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