Fabrication of transparent yttria ceramics through the synthesis of yttrium hydroxide at low temperature and doping by sulfate ions

被引:38
作者
Ikegami, T
Mori, T
Yajima, Y
Takenouchi, S
Misawa, T
Moriyoshi, Y
机构
[1] Natl Inst Res Inorgan Mat, Tsukuba, Ibaraki 3050044, Japan
[2] Hosei Univ, Koganei, Tokyo 1840002, Japan
关键词
transport yttria; sulfate ions; low-temperature synthesis; homogenized densification; house of card; anisotropy; isotropy;
D O I
10.2109/jcersj.107.297
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Thin flakes of yttrium hydroxide coagulate in a manner similar to the houses of cards at an aging temperature lower than room temperature. Increasing the temperature results in an increase in the thickness of the flakes together with collapse of the structure of the house of cards. Relatively thick tablets of yttrium hydroxide appear at temperatures above approximately 50 degrees C. Sulfate ions enhance the sinterability of yttria irrespective of the aging temperature of yttrium hydroxide, and have an influence on the transparency of yttria ceramics. Both the aging of yttrium hydroxide at temperatures lower than room temperature and the doping of sulfate ions are essential to the fabrication of transparent yttria ceramics using the present method.
引用
收藏
页码:297 / 299
页数:3
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