Valence shell charge concentrations and the Dewar-Chatt-Duncanson bonding model

被引：52

作者：

Scherer, W

Eickerling, G

Shorokhov, D

Gullo, E

McGrady, GS

Sirsch, P

机构：

[1] Univ Augsburg, Inst Phys, D-86135 Augsburg, Germany

[2] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[3] Univ New Brunswick, Dept Chem, Fredericton, NB E3B 6E2, Canada

来源：

NEW JOURNAL OF CHEMISTRY | 2006年 / 30卷 / 03期

关键词：

D O I：

10.1039/b515171f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Combined experimental and theoretical charge density studies of the complex [Ni(eta(2)-C2H4) dbpe] (dbpe = (Bu2PCH2CH2PBu2t)-P-t), 1, reveal how the location and magnitude of charge concentrations in the valence shell of the metal atom influence the sigma- and pi-components of the metal - olefin interaction.

引用

页码：309 / 312

页数：4

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