Effects of Impurities on Operational Mechanism of Organic Bulk Heterojunction Solar Cells

被引:50
作者
Kaake, Loren [1 ,2 ]
Dang, Xuan-Dung [1 ,3 ]
Leong, Wei Lin [1 ,2 ]
Zhang, Yuan [1 ,3 ]
Heeger, Alan [1 ,2 ]
Thuc-Quyen Nguyen [1 ,3 ]
机构
[1] Univ Calif Santa Barbara, Ctr Polymers & Organ Solids, Santa Barbara, CA 93106 USA
[2] Univ Calif Santa Barbara, Dept Phys, Santa Barbara, CA 93106 USA
[3] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
关键词
organic solar cells; impurities; open-circuit voltages; charge transfer states; charge generation and recombination; CHARGE RECOMBINATION; EXCITON ANNIHILATION; CRYSTALLIZATION; TRANSPORT; SOLVENT;
D O I
10.1002/adma.201203786
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Photoconductive atomic force microscopy in conjunction with transient absorption spectroscopy and charge transport study were used to investigate the effect of impurities (TCNQ and PC84BM) on the performance of low band gap conjugated polymer and fullerene solar cells to gain insight into whether differing impurity shapes may lead to different loss mechanisms.
引用
收藏
页码:1706 / 1712
页数:7
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