Unprecedented pendant group exchange of a porphyrinato platinum(II) in benzonitrile

被引：6

作者：

Araki, N

Obata, M

Ichimura, A

Mikata, Y

Yano, S ^{[1
]}

机构：

[1] Nara Womens Univ, Grad Sch Humanities & Sci, Div Nat Sci & Ecol Awareness, Nara 6308506, Japan

[2] Osaka City Univ, Grad Sch Sci, Dept Chem, Osaka 5588585, Japan

[3] Nara Womens Univ, KYOSEI Sci Ctr, Nara 6308506, Japan

来源：

CHEMISTRY LETTERS | 2004年 / 33卷 / 04期

关键词：

D O I：

10.1246/cl.2004.450

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

5-(4-cyanophenyl)-10,15,20-triphenylporphyrinato platinum(II) (3) and 5-(4-methoxycarbonylphenyl)-10,15,20-triphenylporphyrinato platinum(II) (2) were isolated from a reaction of 5(4-methoxycarbonylphenyl)-10,15,20-triphenyl porphyrin (1) with K-2[PtCl4] in benzonitrile. Seemingly, 3 was generated through the functional group substitution reaction of the phenyl group of tetraphenylporphyrin during platinum ion insertion into 1 and was characterized by H-1 NMR, mass spectroscopy, elemental analysis, and X-ray crystallography.

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页码：450 / 451

页数：2

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