Magnetoelectric coupling in the cubic ferrimagnet Cu2OSeO3

被引:134
作者
Bos, Jan-Willem G. [1 ,2 ]
Colin, Claire V. [3 ]
Palstra, Thomas T. M. [3 ]
机构
[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
[2] Univ Edinburgh, Ctr Sci Extreme Condit, Edinburgh EH9 3JJ, Midlothian, Scotland
[3] Univ Groningen, Zernike Inst Adv Mat, Solid State Chem Lab, NL-9747 AG Groningen, Netherlands
关键词
D O I
10.1103/PhysRevB.78.094416
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We have investigated the magnetoelectric coupling in the lone pair containing piezoelectric ferrimagnet Cu2OSeO3. Significant magnetocapacitance develops in the magnetically ordered state (T-c = 60 K). We find critical behavior near T-c and a divergence near the metamagnetic transition at 500 Oe. High-resolution x-ray and neutron powder diffraction measurements show that Cu2OSeO3 is metrically cubic down to 10 K but that the ferrimagnetic ordering reduces the symmetry to rhombohedral R3. The metric cubic lattice dimensions exclude a magnetoelectric coupling mechanism involving spontaneous lattice strain, and this is unique among magnetoelectric and multiferroic materials.
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页数:7
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