Combining Visible Light Catalysis and Transition Metal Catalysis for the Alkylation of Secondary Amines

被引：84

作者：

Gao, Xue-Wang ^{[1
,2
]}

Meng, Qing-Yuan ^{[1
,2
]}

Xiang, Ming ^{[1
,2
]}

Chen, Bin ^{[1
,2
]}

Feng, Ke ^{[1
,2
]}

Tung, Chen-Ho ^{[1
,2
]}

Wu, Li-Zhu ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Key Lab Photochem Convers & Optoelect Mat, Tech Inst Phys & Chem, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Univ Chinese Acad Sci, Beijing 100190, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2013年 / 355卷 / 11-12期

基金：

中国国家自然科学基金;

关键词：

alkylation; CH activation; cross-coupling reactions; visible light catalysis; DEHYDROGENATIVE-COUPLING REACTION; C-H BONDS; ALPHA-AMINO; PHOTOREDOX CATALYSIS; HIGHLY EFFICIENT; GLYCINE DERIVATIVES; TERTIARY-AMINES; ADJACENT; NITROGEN; ALKYNYLATION;

D O I：

10.1002/adsc.201300311

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

By combining the visible-light catalyst, Ru(bpy)(3)Cl-2, and transition metal salts, Cu(OTf)(2), we are able to functionalize secondary amines to form Csp3Csp3 bonds with -keto esters efficiently by an aerobic oxidative coupling reaction under visible light irradiation at ambient conditions.

引用

页码：2158 / 2164

页数：7

共 66 条

[1] METALATION AND ELECTROPHILIC SUBSTITUTION OF AMINE DERIVATIVES ADJACENT TO NITROGEN - ALPHA-METALLO AMINE SYNTHETIC EQUIVALENTS [J].