Distance-dependent quenching and enhancing of electrochemiluminescence from a CdS: Mn nanocrystal film by Au nanoparticles for highly sensitive detection of DNA

被引:266
作者
Shan, Yun [1 ]
Xu, Jing-Juan [1 ]
Chen, Hong-Yuan [1 ]
机构
[1] Nanjing Univ, Key Lab Analyt Chem Life Sci, MOE China, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China
关键词
RESONANCE ENERGY-TRANSFER; C-REACTIVE PROTEIN; CDTE QUANTUM DOTS; ELECTROGENERATED CHEMILUMINESCENCE; CARBON-NANOTUBES; FLUORESCENCE; GOLD; HYBRIDIZATION; AMPLIFICATION; SERUM;
D O I
10.1039/b821049g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The quenching of electrochemiluminescence (ECL) from a CdS: Mn nanocrystal film by proximal Au nanoparticles was observed as a result of Forster energy transfer, while an enhancement of ECL takes place after hybridization with target DNA due to the energy transfer of ECL excited surface plasmon resonances in AuNPs to the CdS: Mn NCs at large separation, based on which an ultrasensitive and specific DNA biosensor was constructed.
引用
收藏
页码:905 / 907
页数:3
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