学术探索
学术期刊
新闻热点
数据分析
智能评审

Versatile coordination chemistry towards multifunctional carbon nanotube nanohybrids

被引：57
作者：
Guldi, DM
Rahman, GMA
Qin, SH
Tchoul, M
Ford, WT
Marcaccio, M
Paolucci, D
Paolucci, F
Campidelli, S
Prato, M
机构：
[1] Univ Erlangen Nurnberg, Inst Phys Chem, D-91058 Erlangen, Germany
[2] Oklahoma State Univ, Dept Chem, Stillwater, OK 74078 USA
[3] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
[4] Univ Trieste, Dipartimento Sci Farmaceut, I-34127 Trieste, Italy
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2006年 / 12卷 / 08期
关键词：
charge transfer; donor-acceptor systems; nanotubes; porphyrinoids; radical ions;
D O I：
10.1002/chem.200500933
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dispersible single-walled carbon nanotubes grafted with poly(4-vinylpyridine), SWNT-PVP, were tested in coordination assays with zinc tetraphenylporphyrin (ZnP). Kinetic and spectroscopic evidence corroborates the successful formation of a SWNT-PVP.ZnP nanohybrid. Within this SWNT-PVP-ZnP nanohybrid, static electron-transfer quenching (2.0 +/- 0.1) x 10(9) s(-1) converts the photoexcited-ZnP chromophore into a radical-ion-pair state with a microsecond lifetime, namely one-electron oxidized-ZnP and reduced-SWNT.
引用
收藏
页码：2152 / 2161
页数：10
相关论文
共 122 条
  • [1] Nanotubes from carbon
    Ajayan, PM
    [J]. CHEMICAL REVIEWS, 1999, 99 (07) : 1787 - 1799
  • [2] Sidewall functionalization of single-walled carbon nanotubes with nitrile imines. Electron transfer from the substituent to the carbon nanotube
    Alvaro, M
    Atienzar, P
    de la Cruz, P
    Delgado, JL
    Garcia, H
    Langa, F
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (34) : 12691 - 12697
  • [3] An organically modified single wall carbon nanotube containing a pyrene chromophore:: fluorescence and diffuse reflectance laser flash photolysis study
    Alvaro, M
    Atienzar, P
    Bourdelande, JL
    García, H
    [J]. CHEMICAL PHYSICS LETTERS, 2004, 384 (1-3) : 119 - 123
  • [4] A new pyridyl-substituted methanofullerene derivative.: Photophysics, electrochemistry and self-assembly with zinc(II) meso-tetraphenylporphyrin (ZnTPP)
    Armaroli, N
    Diederich, F
    Echegoyen, L
    Habicher, T
    Flamigni, L
    Marconi, G
    Nierengarten, JF
    [J]. NEW JOURNAL OF CHEMISTRY, 1999, 23 (01) : 77 - 83
  • [5] Layer-by-layer electrostatic self-assembly of polyelectrolyte nanoshells on individual carbon nanotube templates
    Artyukhin, AB
    Bakajin, O
    Stroeve, P
    Noy, A
    [J]. LANGMUIR, 2004, 20 (04) : 1442 - 1448
  • [6] Carbon nanotube electronics
    Avouris, P
    [J]. CHEMICAL PHYSICS, 2002, 281 (2-3) : 429 - 445
  • [7] Covalent chemistry of single-wall carbon nanotubes
    Bahr, JL
    Tour, JM
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (07) : 1952 - 1958
  • [8] Rational chemical strategies for carbon nanotube functionalization
    Banerjee, S
    Kahn, MGC
    Wong, SS
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (09) : 1899 - 1908
  • [9] Single-wall carbon nanotube films for photocurrent generation. A prompt response to visible-light irradiation
    Barazzouk, S
    Hotchandani, S
    Vinodgopal, K
    Kamat, PV
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (44) : 17015 - 17018
  • [10] Carbon nanotube actuators
    Baughman, RH
    Cui, CX
    Zakhidov, AA
    Iqbal, Z
    Barisci, JN
    Spinks, GM
    Wallace, GG
    Mazzoldi, A
    De Rossi, D
    Rinzler, AG
    Jaschinski, O
    Roth, S
    Kertesz, M
    [J]. SCIENCE, 1999, 284 (5418) : 1340 - 1344
12345678910