Molecular structure of [In2(μ, η1-OR) (μ, η2-OR) (η2-OR)3(η1-OR)] R = C2H4NMe2, a pincer ligand

被引:11
作者
Daniele, S
Tcheboukov, D
Hubert-Pfalzgraf, LG
Lecocq, S
机构
[1] Univ Lyon 1, IRC, F-69626 Villeurbanne, France
[2] Univ Lyon 1, Cristallog Lab, F-69622 Villeurbanne, France
关键词
indium; X-ray structure; functional alkoxide; copper;
D O I
10.1016/S1387-7003(02)00400-8
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Functional indium [In(OR)(3)](m) alkoxides (R = C2H4OMe, C2H4NMe2) have been obtained by alcoholysis of In[N(SiMe3)(2)](3) and characterised by elemental analysis, FT-IR and NMR spectroscopy. The 2-dimethylaminoethoxide was characterised by X-ray diffraction. It corresponds to the association of two InO6 octahedra giving the unsymmetrical dimer [In-2(mu, eta(1)-OR)(mu, eta(2)-OR)(eta(2)-OR)(3)(eta(1)-OR)] (2). 2 was used as a pincer ligand toward Cu(acac)(2). (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:347 / 350
页数:4
相关论文
共 34 条
  • [1] PREPARATION AND REACTIONS OF GALLIUM ALKOXIDES
    BINDAL, SR
    MATHUR, VK
    MEHROTRA, RC
    [J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (06): : 863 - &
  • [2] PENTANUCLEAR OXOALKOXIDE CLUSTERS OF SCANDIUM, YTTRIUM, INDIUM AND YTTERBIUM, X-RAY CRYSTAL-STRUCTURES OF [M5(MU5-O)(MU3-OPRI)4 (MU2-OPRI)4(OPRI)5] (M = IN, YB)
    BRADLEY, DC
    CHUDZYNSKA, H
    FRIGO, DM
    HAMMOND, ME
    HURSTHOUSE, MB
    MAZID, MA
    [J]. POLYHEDRON, 1990, 9 (05) : 719 - 726
  • [3] CHEMISTRY OF SILICON-NITROGEN COMPOUNDS .107. SYNTHESIS, VIBRATION SPECTRA AND NORMAL COORDINATE ANALYSIS OF DISILYLAMIDES OF GROUP-III - M[N(SIME3)2]3 WHERE M=AL, GA AND IN
    BURGER, H
    CICHON, J
    GOETZE, U
    WANNAGAT, U
    WISMAR, HJ
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 33 (01) : 1 - &
  • [4] CAULTON KG, 1989, CHEM REV, V89, P963
  • [5] CHATTERJEE S, 1976, J INDIAN CHEM SOC, V53, P867
  • [6] DANIELE S, UNPUB J MAT CHEM
  • [7] Sol-gel deposited Sb-doped tin oxide films
    Guglielmi, M
    Menegazzo, E
    Paolizzi, M
    Gasparro, G
    Ganz, D
    Pütz, J
    Aegerter, MA
    Hubert-Pfalzgraf, L
    Pascual, C
    Durán, A
    Willems, HX
    Van Bommel, M
    Büttgenbach, L
    Costa, L
    [J]. JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1998, 13 (1-3) : 679 - 683
  • [8] Guillon H, 2000, EUR J INORG CHEM, P1243
  • [9] HARPER JA, 1994, MAT RES SOC B, V8, P41
  • [10] Hathaway B. J., 1987, COMPREHENSIVE COORDI, V5, P533