Shell morphology of core-shell latexes based on conductive polymers

被引：37

作者：

Huijs, FM

Vercauteren, FF

de Ruiter, B

Kalicharan, D

Hadziioannou, G

机构：

[1] Univ Groningen, Ctr Mat Sci, Dept Polymer Chem, NL-9747 AG Groningen, Netherlands

[2] TNO, Ind Technol Inst, Div Mat Technol, NL-5600 HE Eindhoven, Netherlands

[3] Univ Groningen, Lab Cell Biol & Electron Microscopy, NL-9713 EZ Groningen, Netherlands

来源：

SYNTHETIC METALS | 1999年 / 102卷 / 1-3期

关键词：

chemical synthesis; control of interface structure and morphology; scanning electron microscopy; coatings; polypyrrole and derivatives; phase-segregated composite interface;

D O I：

10.1016/S0379-6779(98)01444-1

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Core-shell latexes with a conductive shell can be used to prepare transparent conducting layers. We have focussed on the relation between the conducting polymer content and the shell morphology and on its influence on conductivity. At low polypyrrole (PPy) concentrations the shell has a smooth surface as is shown using SEM, and the conductivity correlates with the PPy content. The percolation threshold is 0.25 wt% PPy, indicating a theoretical shell thickness of 6 Angstrom. At higher PPy loadings different morphologies are formed and the conductivity is almost independent of the PPy content. TEM micrographs of sections of the dried conductive latex embedded in epoxy give the conclusive evidence for the core-shell structure.

引用

页码：1151 / 1152

页数：2

共 5 条

[1]

HATANO M, 1961, J POLYM SCI, V51, P526

[2]

HUIJS FM, UNPUB

[3]

HUIJS FM, 1997, MAT FUNCT DES P EUR, V3, P417

[4] SYNTHESIS AND CHARACTERIZATION OF MICROMETER-SIZED POLYPYRROLE-COATED POLYSTYRENE LATEXES [J].