Recent advances in olefin metathesis by molybdenum and tungsten imido alkylidene complexes

被引：154

作者：

Schrock, RR ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 213卷 / 01期

关键词：

olefin metathesis; molybdenum imido alkylidene complexes; tungsten imido alkylidene complexes;

D O I：

10.1016/j.molcata.2003.10.060

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Recent advances in olefin metathesis studies include the preparation of catalysts "in situ," supported catalysts, and tungsten-based catalysts, and observation of molybdacyclobutane complexes, molybdacyclopentane complexes, base-free methylene complexes, and ethylene complexes such as Mo(N-2,6-Cl2C6H3)(CH2=CH2)[rac-Biphen](Et2O). (C) 2004 Elsevier B.V. All rights reserved.

引用

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页码：21 / 30

页数：10

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