Effect of ordering on spinodal decomposition of liquid-crystal/polymer mixtures

被引:62
作者
Lapeña, AM [1 ]
Glotzer, SC
Langer, SA
Liu, AJ
机构
[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
[2] Natl Inst Stand & Technol, Div Polymers, Gaithersburg, MD 20899 USA
[3] Natl Inst Stand & Technol, Ctr Theoret & Computat Mat Sci, Gaithersburg, MD 20899 USA
[4] Natl Inst Stand & Technol, Informat Technol Lab, Gaithersburg, MD 20899 USA
来源
PHYSICAL REVIEW E | 1999年 / 60卷 / 01期
关键词
D O I
10.1103/PhysRevE.60.R29
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
Partially phase-separated liquid-crystal/polymer dispersions display highly fibrillar domain morphologies that are dramatically different from the typical structures found in isotropic mixtures. To explain this, we numerically explore the coupling between phase ordering an phase-separation kinetics in model two-dimensional fluid mixtures phase separating into a nematic phase, rich in liquid crystal, coexisting with an isotropic phase, rich in polymer. We find that phase ordering can lead to fibrillar networks of the minority polymer-rich phase. [S1063-651X(99)51207-5].
引用
收藏
页码:R29 / R32
页数:4
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