Ultrafine SnO2 nanoparticle loading onto reduced graphene oxide as anodes for sodium-ion batteries with superior rate and cycling performances

被引：287

作者：

Wang, Yun-Xiao ^{[1
,2
]}

Lim, Young-Geun ^{[1
,3
]}

Park, Min-Sik ^{[1
]}

Chou, Shu-Lei ^{[2
]}

Kim, Jung Ho ^{[2
]}

Liu, Hua-Kun ^{[2
]}

Dou, Shi-Xue ^{[2
]}

Kim, Young-Jun ^{[1
]}

机构：

[1] Korea Elect Technol Inst, Adv Batteries Res Ctr, 68 Yatap Dong, Songnam 463816, Gyeonggi Do, South Korea

[2] Univ Wollongong, ISEM, Wollongong, NSW 2519, Australia

[3] Korea Univ, Dept Mat Sci & Engn, Seoul 136713, South Korea

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2014年 / 2卷 / 02期

基金：

澳大利亚研究理事会;

关键词：

SOLID-ELECTROLYTE INTERPHASE; HIGH-CAPACITY; LITHIUM-ION; NEGATIVE ELECTRODE; TIN-NANOPARTICLES; INSERTION; CHALLENGES; NANOCOMPOSITES; CYCLABILITY; NANOWIRES;

D O I：

10.1039/c3ta13592f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A structured SnO2-reduced graphene oxide (RGO) nanocomposite has been synthesized with SnO2 nanoparticles (similar to 5 nm) anchored on a RGO framework. It has been successfully applied as an anode material in sodium-ion batteries. The electrode delivers a reversible Na-storage capacity of 330 mA h g(-1) with an outstanding capacity retention of 81.3% over 150 cycles. Moreover, it possesses a relatively good rate capability, exhibiting a capacity retention of 25.8% at high rate (1000 mA h g(-1)). With its combined advantages of low cost and environmental benignity, the SnO2-RGO nanocomposite would be a promising anode for Na-ion batteries.

引用

页码：529 / 534

页数：6

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