Synthesis and characterization of polymers containing linear sugar moieties as side groups

被引：29

作者：

Narain, R

Jhurry, D ^{[1
]}

Wulff, G

机构：

[1] Univ Mauritius, Fac Sci, Dept Chem, Reduit, Mauritius

[2] Univ Dusseldorf, Inst Organ Chem & Macromol Chem, D-40225 Dusseldorf, Germany

来源：

EUROPEAN POLYMER JOURNAL | 2002年 / 38卷 / 02期

关键词：

vinylsugars; water-soluble homopolymers; copolymers;

D O I：

10.1016/S0014-3057(01)00172-0

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of a water-soluble monomer, namely 4-vinylphenyl-D-gluco(D-manno)hexitol (4) derived from D-gluconolactone, is here presented. The homopolymerization of the vinylsugar has been conducted in both aqueous and organic media using free-radical initiators. High-molar-mass water-soluble polymers are obtained. The copolymerization behavior of the vinylphenyl sugar monomer with a hydrophilic monomer such as acrylamide, as well as with a hydrophobic monomer such as styrene, has been investigated. Statistical- and block-type copolymers have thus been prepared. The structures of the polymers were confirmed by NMR and their thermal properties examined by DSC. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：273 / 280

页数：8

共 11 条

[1]

JHURRY D, 1992, MAKROMOL CHEM, V193, P2997

[2] The synthesis of polymerizable vinyl sugars [J].