Model insect antifeedants. Synthesis of azadiradione fragments through acyl radicals cyclizations and stannane coupling reactions

被引：19

作者：

FernandezMateos, A

Coca, GP

Gonzalez, RR

Hernandez, CT

机构：

[1] Depto. de Quim. Orgánica, Facultad de C. Químicas, Universidad de Salamanca, 37008 Salamanca

来源：

TETRAHEDRON | 1996年 / 52卷 / 13期

关键词：

D O I：

10.1016/0040-4020(96)00149-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A diastereoselective and versatile synthesis of the model insect antifeedant 16 related to azadiradione has been achieved in nine steps starting from alpha-cyclocitral 1. The key steps involve intramolecular alkene addition of an acyl radical and a Stille coupling reaction of a vinyl iodide with a stannylfuran.

引用

页码：4817 / 4828

页数：12

共 31 条

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