Enzymatic kinetic resolution of pantolactone: relevance to chiral auxiliary chemistry

被引：22

作者：

Haughton, L ^{[1
]}

Williams, JMJ ^{[1
]}

Zimmermann, JA ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 08期

关键词：

D O I：

10.1016/S0957-4166(00)00130-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Racemic pantolactone was converted into either enantiomerically enriched pantolactone acetate or pantolactone acrylate by an enzyme-catalysed kinetic resolution process. Pantolactone is known to be a good auxiliary for acrylate ill the Diels-Alder reaction. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：1697 / 1701

页数：5

共 10 条

[1] Athawale V, 2000, SYNLETT, P225
[2] RESOLUTION OF SECONDARY ALCOHOLS USING LIPASE IN DIISOPROPYL ETHER
BEVINAKATTI, HS
BANERJI, AA
NEWADKAR, RV
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (10) : 2453 - 2455
[3] Enantioselectivity of enzymatic acylation of some structurally various racemic alcohols in anhydrous aprotic media
Gamalevich, GD
Serebryakov, EP
[J]. RUSSIAN CHEMICAL BULLETIN, 1997, 46 (01) : 171 - 183
[4] CHEMOENZYMATIC SYNTHESIS OF OPTICALLY-ACTIVE (METH)ACRYLIC POLYMERS
MARGOLIN, AL
FITZPATRICK, PA
DUBIN, PL
KLIBANOV, AM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (12) : 4693 - 4694
[5] DIASTEREOFACE-DISCRIMINATIVE METAL COORDINATION IN ASYMMETRIC-SYNTHESIS - D-PANTOLACTONE AS PRACTICAL CHIRAL AUXILIARY FOR LEWIS ACID-CATALYZED DIELS-ALDER REACTIONS
POLL, T
SOBCZAK, A
HARTMANN, H
HELMCHEN, G
[J]. TETRAHEDRON LETTERS, 1985, 26 (26) : 3095 - 3098
[6] Preparative biotransformations
Roberts, SM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1999, (01): : 1 - +
[7] Optical resolution of pantolactone by a novel fungal enzyme, lactonolaydrolase
Shimizu, S
Kataoka, M
[J]. ENZYME ENGINEERING XIII, 1996, 799 : 650 - 658
[8] CROSS-LINKED ENZYME CRYSTALS AS ROBUST BIOCATALYSTS
STCLAIR, NL
NAVIA, MA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (18) : 7314 - 7316
[9] Protein crystals as novel microporous materials
Vilenchik, LZ
Griffith, JP
St Clair, N
Navia, MA
Margolin, AL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (18) : 4290 - 4294
[10] WHITESELL JK, 1990, ORG SYNTH, V69, P1

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