Preparation and characterization of high metal content Pt-Ru alloy catalysts on various carbon blacks for DMFCs

被引：40

作者：

Han, Kookil ^{[1
]}

Lee, Jaeseung ^{[1
]}

Kim, Hasuck ^{[1
]}

机构：

[1] Seoul Natl Univ, Dept Chem, Seoul 151747, South Korea

来源：

ELECTROCHIMICA ACTA | 2006年 / 52卷 / 04期

关键词：

DMFC; catalyst; supporting material; high metal content; agglomeration;

D O I：

10.1016/j.electacta.2006.03.098

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

High metal content Pt-Ru alloy catalysts (80 and 90 wt.%) with various carbons were prepared by the colloidal method without increasing particle size. As increasing the specific areas Of Supporting materials, catalysts exhibited homogeneous dispersions. The 90 wt.% Pt-Ru/Ketjen Black showed the best performance as the anode catalyst in unit cell and the 80 wt.% Pt-Ru/Ketjen Black in electrochemical experiments. This difference comes from types of electrolytes, i.e. liquid and solid. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：1697 / 1702

页数：6

共 17 条

[1] Investigation of direct methanol fuel cells based on unsupported Pt-Ru anode catalysts with different chemical properties
Aricò, AS
Cretì, P
Modica, E
Monforte, G
Baglio, V
Antonucci, V
[J]. ELECTROCHIMICA ACTA, 2000, 45 (25-26) : 4319 - 4328
[2] Graphite nanofibers as an electrode for fuel cell applications
Bessel, CA
Laubernds, K
Rodriguez, NM
Baker, RTK
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (06): : 1115 - 1118
[3] FORMATION OF COLLOIDAL TRANSITION-METALS IN ORGANIC PHASES AND THEIR APPLICATION IN CATALYSIS
BONNEMANN, H
BRIJOUX, W
BRINKMANN, R
DINJUS, E
JOUSSEN, T
KORALL, B
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (10): : 1312 - 1314
[4] THE APPLICATION OF RADIOGRAPHY TO THE STUDY OF THE STRUCTURE AND OPERATION OF POROUS ELECTRODES
BONNEMAY, M
BRONOEL, G
LEVART, E
PESLERBE, G
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1964, 111 (03) : 265 - 269
[5] Metal-nanocluster-filled carbon nanotubes: Catalytic properties and possible applications in electrochemical energy storage and production
Che, GL
Lakshmi, BB
Martin, CR
Fisher, ER
[J]. LANGMUIR, 1999, 15 (03) : 750 - 758
[6] Performance and impedance under various catalyst layer thicknesses in DMFC
Lee, JS
Han, KI
Park, SO
Kim, HN
Kim, H
[J]. ELECTROCHIMICA ACTA, 2004, 50 (2-3) : 807 - 810
[7] Carbon nanotubes as support for cathode catalyst of a direct methanol fuel cell
Li, WZ
Liang, CH
Qiu, JS
Zhou, WJ
Han, HM
Wei, ZB
Sun, GQ
Xin, Q
[J]. CARBON, 2002, 40 (05) : 791 - 794
[8] Carbon supported and unsupported Pt-Ru anodes for liquid feed direct methanol fuel cells
Liu, L
Pu, G
Viswanathan, R
Fan, QB
Liu, RX
Smotkin, ES
[J]. ELECTROCHIMICA ACTA, 1998, 43 (24) : 3657 - 3663
[9] Mesocarbon microbeads supported Pt-Ru catalysts for electrochemical oxidation of methanol
Liu, YC
Qiu, XP
Huang, YQ
Zhu, WT
[J]. JOURNAL OF POWER SOURCES, 2002, 111 (01) : 160 - 164
[10] Effects of Nafion as a binding agent for unsupported nanoparticle catalysts
McGovern, MS
Garnett, EC
Rice, C
Masel, RI
Wieckowski, A
[J]. JOURNAL OF POWER SOURCES, 2003, 115 (01) : 35 - 39

← 1 2 →